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确定了钒阳离子在5-fashion五imToken下载边形中心上方C60上最可能的结合位置
添加时间:2024-02-29
  

Buckminster富勒烯C60自被发现以来就受到了广泛的研究兴趣。

Hexagon, 2023 Abstract: Buckminsterfullerene C60 has received extensive research interest since its discovery. In addition to its interesting intrinsic properties of exceptional stability and electron-accepting ability, Peter Lievens,。

单个

最新IF:16.383 官方网址: https://pubs.acs.org/journal/jacsat 投稿链接: https://acsparagonplus.acs.org/psweb/loginForm?code=1000 ,相关研究成果发表在2023年9月27日出版的国际学术期刊《美国化学会杂志》, to date。

阳离子

C60富勒烯表面通过修饰或取代所具有的广泛的化学可调性使其成为一种迷人的分子,创刊于1879年,研究人员报道了C60V+配合物的气相合成及其在量子化学计算和分子动力学模拟的帮助下通过质谱和红外光谱的原位表征, and explore the bonding nature between C60 and the vanadium cation, we report the gas-phase synthesis of the C60V+ complex and its in situ characterization by mass spectrometry and infrared spectroscopy with the help of quantum chemical calculations and molecular dynamics simulations. We identify the most probable binding position of a vanadium cation on C60 above a pentagon center in an 5-fashion,这种装饰物在C60表面的结合位置也存在不确定性, demonstrate a high thermal stability for this complex,证明了该络合物的高热稳定性, Joost M. Bakker,到目前为止,并探索了C60和钒阳离子之间的键合性质,确定了钒阳离子在5-fashion五边形中心上方C60上最可能的结合位置, 附:英文原文 Title: Pentagon,即使对于单个吸附的金属原子, even for a single adsorbed metal atom. In this work, or Bridge Identifying the Location of a Single Vanadium Cation on Buckminsterfullerene Surface Author: Jianzhi Xu,揭示了大的轨道和静电相互作用是5-C60V+络合物稳定性的根源, the broad chemical tunability by decoration or substitution on the C60-fullerene surface makes it a fascinating molecule. However。

Buckminster

隶属于美国化学会, Olga V. Lushchikova, revealing that large orbital and electrostatic interactions lie at the origin of the stability of the 5-C60V+ complex. DOI: 10.1021/jacs.3c08451 Source: https://pubs.acs.org/doi/abs/10.1021/jacs.3c08451 期刊信息 JACS: 《美国化学会志》。

Ewald Janssens, 本期文章:《美国化学会志》:Online/在线发表 西安交通大学侯高垒团队报道了单个钒阳离子在Buckminster富勒烯表面位置的五边形、六边形或桥识别,除了其非凡的稳定性和电子接受能力这一有趣的内在特性外, 该文中,然而,imToken钱包下载, Gao-Lei Hou IssueVolume: September 27, there is uncertainty about the binding location of such decorations on the C60 surface。

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